Nature: Electrostatic jet deflection 3D printing sub-micron structure, the speed is 1,000 to 10,000
In the paper detailing this new technology, the authors explained that they created the electrostatic jet deflection
method to overcome the limitations of existing rapid prototyping manufacturing technology in terms of production
speed. From their tests, the researchers found that the electrostatic jet deflection method can achieve 3D printing of
objects with sub-micron features by stacking nanofibers at a layer-by-layer frequency of up to 2000 Hz.
The achieved jetting speed and layer-by-layer frequency are equivalent to a printing speed of up to 0.5 m per
second in the planar direction and a printing speed of 0.4 mm per second in the vertical direction. The researchers
say this is "faster than the same precision feature size technology" Three to four orders of magnitude".
△Schematic diagram of 3D printed wall
Improve 3D printing process
The researchers first described the benefits of rapid prototyping manufacturing technology for today’s production,
and wrote: "Rapid prototyping manufacturing has become a new paradigm for distributed production of customized
products, in terms of geometric freedom of design, material utilization, and shortened delivery. It has advantages in
terms of period."
Nevertheless, the existing 3D printing process still has many researches that can be improved. For example,
researchers in Austria have explored the need for necessary improvements in material extrusion-based rapid
prototyping manufacturing methods (ME-AM/FDM/FFF) to "meet the challenges of complex industrial applications."
Other research focuses on the effect of fast printing speed in the binder jet process, especially in terms of surface
roughness and density uniformity.
Like many research papers aiming to improve the existing rapid prototyping manufacturing process, the author
stated that there are some limitations surrounding the current 3D printing technology, namely production speed,
material availability and combination, and control of the microstructure of the material. Realize function control.
"In addition," the author added, "For true distributed production, the cost and complexity of manufacturing
equipment capable of producing sub-micron features are prohibitive."
△ac Schematic diagram of experimental PEO-PEDOT:PSS pattern (above) and optical photo of experimental PEO-
PEDOT: PSS pattern (below): a fiber bending obtained without jet deflection; b on a mechanical platform Use the
sawtooth pattern obtained by 1D jet deflection on the axis of translation; c use the circular pattern obtained by 2D jet
deflection. d, e Use two jet deflection electrodes to define the pattern and the mechanical stage to switch the
substrate between printing events. The mechanical stage to switch the substrate, prints an optical photo of more
complex 2D patterns. These patterns were printed using 4.7wt% PEO ink containing Ag NPs. Scale bars (D, E): 1 mm.
In particular, nozzle-based 3D printing technology provides a good example. This process provides "unparalleled
versatility" because it can make objects with different degrees of materials, from polymers, metals, ceramics, wood,
Even different materials such as biological tissues. "This incomparable material versatility stems from the use of metal
or polymer melts or solvent-based inks. The formulation can contain any ingredient in the form of ions, molecules,
nanoparticles, and even living cells." The researchers explained.
However, the current nozzle-based 3D printing technology is relatively slow and the printing resolution is limited
because the width of the printed lines is related to the nozzle aperture, which is usually more than tens of microns.
Even if a smaller nozzle aperture is used, frequent clogging and high viscosity loss are likely to occur during the
printing process.
Using electrostatic jet deflection technology
The author proposes that an electro-hydrodynamic (EHD) jetting strategy is unique compared to other nozzle-
based 3D printing methods. In 2019, researchers at ETH Zurich demonstrated this. "EHD jet can print sub-micron
structures without the risk of nozzle clogging, because it can use a variety of inks to produce nano-scale jets from a
wide nozzle aperture, with a viscosity of more than several orders of magnitude."
△Schematic diagram of 3D printed cylinder. The picture comes from Nature Communications.
However, the EHD jet technology has not yet been fully developed for wide applications, because the electrochemical
jet is too fast and the mechanical stage is relatively slow to collect materials accurately. "The current EHD jet-based
system uses a mechanical stage to position the printing material. However, the mechanical stage can only match the
huge speed of the electrochemical jet in a long straight line, but it cannot achieve this speed when printing small and
complex patterns. Huge acceleration." The author added.
In order to overcome the limitations of the EHD printing process, the researchers proposed to use electrodes to
modify the electric field. Using a traditional EHD printer, the researchers placed the electrode around the jet and
controlled the voltage of the electrode to continuously adjust its trajectory with a lateral acceleration of up to 106
m/s. This allows the jet to achieve ultra-fast electrostatic deflection, allowing nanofibers to be stacked to print 3D
objects with sub-micron features.
From their tests, the researchers were able to 3D print objects with materials deposited layer by layer, up to 100
microns in height, with a very high aspect ratio and high speed. Fast jetting and these high layer-by-layer frequencies
translate into a printing speed of 0.5 m/s in the plane and 0.4 mm/s out of the plane, that is, in the vertical direction,
compared to extrusion and on-demand dripping EHD technology, the same size is produced When characterizing,
it’s three to four orders of magnitude faster.
At the end of the paper, the researchers stated that the advantages of EHD jet deflection printing that they
demonstrated in the paper may bring this technology closer to the ultra-fast and fast additive microfabrication
of 3D objects.
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